Numéro |
J. Phys. III France
Volume 3, Numéro 5, May 1993
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Page(s) | 945 - 960 | |
DOI | https://doi.org/10.1051/jp3:1993174 |
J. Phys. III France 3 (1993) 945-960
Theory of oxygen tracer diffusion along grain boundaries and in the bulk in two-stage oxidation experiments. Part II: analysis of type B regime
Yu. M. Mishin and G. BorchardtSonderforschungsbereich 180 and Institut für Allgemeine Metallurgie, Technische Universität Clausthal, Robert-Koch-Str. 42, D-3392 Clausthal-Zellerfeld, Germany
(Received 14 September 1992, accepted 4 February 1993)
Abstract
In part I of this work a model of
18O transport in a growing oxide film with parallel
grain boundaries has been proposed, and analysis of type A and type C regimes has
been carried out. In this paper the analysis is extended to the intermediate, type B
regime. We derive an analytical solution of the model, which describes both B and C type
regimes as particular cases, and calculate tracer penetration profiles along grain
boundaries depending on the drift velocity and time. The results of penetration profile
analysis are presented as kinetic diagrams allowing to predict kinetic regimes of
18O
transport under various conditions. We also discuss methods of profile processing for
diffusion parameters determination. The analytical solutions obtained and the kinetic
diagrams constructed can be used for the treatment of experimental profiles measured
in two-stage oxidation experiments.
© Les Editions de Physique 1993